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By Stuart A. Rice

This sequence offers the chemical physics box with a discussion board for severe, authoritative reviews of advances in each quarter of the self-discipline. quantity 129 within the sequence maintains to document fresh advances with major, up to date chapters by way of across the world well-known researchers.

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The diffusion front for each layer is defined using the ‘‘seawater’’ methodology of Sapoval et al. [161]. 36. PFPE Z 3D simulation results: J=kB T ¼ 2, A=kB T ¼ 1000, 105 lattice steps. 37. PFPE Zdol 3D simulation results: J=kB T ¼ 1, A=kB T ¼ 1000, K0 =kB T ¼ 4, W0 =kB T ¼ 4, d ! 1, 105 lattice steps. Here, Df is the fractal dimension, which differs for the monolayer and multilayer situations, implying that Df is determined not only by lateral movement (virtually independent of layer thickness) but also by a cascade effect from overlying layers.

From the intercept and slope, we obtain [Z] and kH . 24. Reduced viscosities for Zdol for three different solvents. 28 myung s. 00 and the hydrodynamic radii RH [111] of Zdol4000 in three different solvents are summarized in Table I. 5. However, for a colloidal suspension of nonspherical particles, ½ZŠ > 2:5. Jeffery [112] obtained the viscosity of an ellipsoidal particle suspension under shear. Incorporating Jeffery’s results of velocity fields around the particle, Simha [113] obtained expressions for two explicit limiting cases of ellipsoids.

41 is a schematic of the potential functions given in Eqs. 35). We assumed that all polymer chains in the system have the same number of beads, that is, that they are monodisperse. The number of beads Np in each polymer chain is chosen as Np ¼ 6, 10, or 16. PFPEs have rigid fluorocarbon backbone units connected via ether bonds, which give flexibility to the chain while keeping PFPEs stable in a liquid state at room temperature. The beads in our model reproduce the rigid units and are connected only via their 46 myung s.

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